相平衡.相图和相变-其热力学基础-第二版-(影印版)
相平衡.相图和相变-其热力学基础-第二版-(影印版)作者:希勒特 开 本:16开 书号ISBN:9787301245552 定价:89.0 出版时间:2014-08-01 出版社:北京大学出版社 |
16.6 phase equilibrium at crystal/fluid interface
16.7 equilibrium at curved interfaces with regard to composition
16.8 equilibrium for crystalline inclusions with regard to composition
16.9 surface segregation
16.10 coherency within a phase
16.11 coherency between two phases
16.12 solute drag
17 kinetics of transport processes
17.1 thermal activation
17.2 diffusion coefficients
17.3 stationary states for transport processes
17.4 local volume change
17.5 composition of material crossing an interface
17.6 mechanisms of interface migration
17.7 balance of forces and dissipation
18 methods of modelling
18.1 general principles
18.2 choice of characteristic state function
18.3 reference states
18.4 representation of gibbs energy of formation
18.5 use of power series in t
18.6 representation of pressure dependence
18.7 application of physical models
18.8 ideal gas
18.9 real gases
18.10 mixtures of gas species
18.11 black-body radiation
18.12 electron gas
19 modelling of disorder
19.1 introduction
19.2 thermal vacancies in a crystal
19.3 topological disorder
19.4 heat capacity due to thermal vibrations
19.5 magnetic contribution to thermodynamic properties
19.6 a simple physical model for the magnetic contribution
19.7 random mixture of atoms
19.8 restricted random mixture
19.9 crystals with stoichiometric vacancies
19.10 interstitial solutions
20 mathematical modelling of solution phases
20.1 ideal solution
20.2 mixing quantities
20.3 excess quantities
20.4 empirical approach to substitutional solutions
20.5 real solutions
20.6 applications of the gibbs–duhem relation
20.7 dilute solution approximations
20.8 predictions for solutions in higher-order systems
20.9 numerical methods of predictions for higher-order systems
21 solution phases with sublattices
21.1 sublattice solution phases
21.2 interstitial solutions
21.3 reciprocal solution phases
21.4 combination of interstitial and substitutional solution
21.5 phases with variable order
21.6 ionic solid solutions
22 physical solution models
22.1 concept of nearest-neighbour bond energies
22.2 random mixing model for a substitutional solution
22.3 deviation from random distribution
22.4 short-range order
22.5 long-range order
22.6 long- and short-range order
22.7 the compound energy formalism with short-range order
22.8 interstitial ordering
22.9 composition dependence of physical effects
references
index
自然科学 物理学 热学与物质分子运动论
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